Methyl 4-bromo-3-hydroxybenzoate

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Methyl 4-bromo-3-hy­droxy­benzoate

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In the mol-ecule of the title compound, C(13)H(13)BrN(2)O(2)S, the dihedral angle formed by the pyridine and benzene rings is 66.87 (3)°. An intra-molecular N-H⋯Br hydrogen bond is observed. In the crystal structure, N-H⋯O hydrogen bonds, C-H⋯π inter-actions and aromatic π-π stacking inter-actions [centroid-centroid distance = 3.757 (14) Å] link the mol-ecules into a three-dimensional network.

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In the title compound, C(16)H(13)BrO(2)S, the 4-methyl-phenyl ring makes a dihedral angle of 87.83 (6)° with the mean plane [mean deviation = 0.007 (1) Å] of the benzofuran fragment. In the crystal, mol-ecules are linked by weak C-H⋯O hydrogen bonds and Br⋯O contacts [3.099 (2) Å]. The crystal structure also exhibits π-π inter-actions between the furan and benzene rings of neighbouring mol-ecul...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2010

ISSN: 1600-5368

DOI: 10.1107/s1600536810051445